In physics, temperature is a physical property of a system that underlies the common notions of hot and cold; something that feels hotter generally has the greater temperature. Temperature is one of the principal parameters of thermodynamics. On the macroscopic scale, temperature is the unique physical property that determines the direction of heat flow between two objects placed in thermal contact. If no heat flow occurs, the two objects have the same temperature; otherwise heat flows from the hotter object to the colder object. This is the content of the zeroth law of thermodynamics. On the microscopic scale, temperature can be defined as the average energy in each degree of freedom in the particles in a system- because temperature is a statistical property, a system must contain a few particles for the question as to its temperature to make any sense. For a solid, this energy is found in the vibrations of its atoms about their equilibrium positions. In an ideal monatomic gas, energy is found in the translational motions of the particles; with molecular gases, vibrational and rotational motions also provide thermodynamic degrees of freedom.

Temperature is measured with thermometers that may be calibrated to a variety of temperature scales. In most of the world (except for Belize, Myanmar, Liberia and the United States), the Celsius scale is used for most temperature measuring purposes. The entire scientific world (these countries included) measures temperature using the Celsius scale and thermodynamic temperature using the kelvin scale, which is just the Celsius scale shifted downwards so that 0 K= −273.15 °C, or absolute zero. Many engineering fields in the U.S., especially high-tech ones, also use the kelvin and degrees Celsius scales. Other engineering fields in the U.S. also rely upon the Rankine scale (a shifted Fahrenheit scale) when working in thermodynamic-related disciplines such as combustion.

Overview

Intuitively, temperature is the measurement of how hot or cold something is, although the most immediate way in which we can measure this, by feeling it, is unreliable, resulting in the phenomenon of felt air temperature, which can differ at varying degrees from actual temperature. On the molecular level, temperature is the result of the motion of particles which make up a substance. Temperature increases as the energy of this motion increases. The motion may be the translational motion of the particle, or the internal energy of the particle due to molecular vibration or the excitation of an electron energy level. Although very specialized laboratory equipment is required to directly detect the translational thermal motions, thermal collisions by atoms or molecules with small particles suspended in a fluid produces Brownian motion that can be seen with an ordinary microscope. The thermal motions of atoms are very fast and temperatures close to absolute zero are required to directly observe them. For instance, when scientists at the NIST achieved a record-setting cold temperature of 700 nK (1 nK = 10⁻⁹ K) in 1994, they used optical lattice laser equipment to adiabatically cool caesium atoms. They then turned off the entrapment lasers and directly measured atom velocities of 7 mm per second in order to calculate their temperature.