Propane is a three-carbon alkane, normally a gas, but compressible to a liquid that is transportable. It is derived from other petroleum products during oil or natural gas processing. It is commonly used as a fuel for engines, barbecues, and home heating systems.

When used as vehicle fuel, it is commonly known as liquified petroleum gas (LPG or LP-gas), which can be a mixture of propane along with small amounts of propylene, butane, and butylene. The odorant ethanethiol is also added so that people can easily smell the gas in case of a leak.

Properties and reactions

Propane undergoes combustion reactions in a similar fashion to other alkanes. In the presence of excess oxygen, propane burns to form water and carbon dioxide.

C₃H₈ + 5 O₂ → 3 CO₂ + 4 H₂O + heat

Propane + Oxygen → Carbon Dioxide + Water

When not enough oxygen is present for complete combustion, incomplete combustion occurs when propane burns and forms water, carbon monoxide, carbon dioxide, and carbon.

C₃H₈ + 3.5 O₂ → CO₂ + CO + C + 4 H₂O + heat

Propane + Oxygen → Carbon Dioxide + Carbon Monoxide + Carbon + Water

Unlike natural gas, propane is heavier than air (1.5 times as dense). In its raw state, propane sinks and pools at the floor. Liquid propane will flash to a vapor at atmospheric pressure and appears white due to moisture condensing from the air.

When properly combusted, propane produces about 93 kJ/L. The gross heat of combustion of one normal cubic meter of propane is around 50 megajoules (≈13.8 kWh), i.e. 50 kJ/L.Fact: date=June 2008

Propane is nontoxic; however, when abused as an inhalant it poses a mild asphyxiation risk through oxygen deprivation. Commercial products contain hydrocarbons beyond propane, which may increase risk. Commonly stored under pressure at room temperature, propane and its mixtures expand and cool when released and may cause mild frostbite.

Propane combustion is much cleaner than gasoline combustion, though not as clean as natural gas combustion. The presence of C-C bonds, plus the multiple bonds of propylene and butylene, create organic exhausts besides carbon dioxide and water vapor during typical combustion. These bonds also cause propane to burn with a visible flame.

Greenhouse gas emissions factors for propane are 62.7 kg CO₂/ mBTU or 1.55 kg of CO₂ per litre or 73.7 kg / GJ.

Uses

Propane is used as fuel in cooking on many barbecues, portable stoves and in motor vehicles. The ubiquitous 4.73-gallon (20 lb.) steel container is often dubbed a "barbecue tank". Propane remains a popular choice for barbecues and portable stoves because its low boiling point (-42°C) allows it to vaporize once it is released from its pressurized container. This results in a clean-burning fuel that doesn't require a lot of equipment to vaporize. A simple nozzle will suffice. Propane powers some locomotives, buses, forklifts, taxis and ice resurfacing machines and is used for heat and cooking in recreational vehicles and campers. In many rural areas of North America, propane is used in furnaces, cooking stoves, water heaters, laundry dryers, and other heat-producing appliances. As of 2000, 6.9 million American households use propane as their primary heating fuel.