thumb|right|The repeating unit of the polymer polypropylene A polymer (from Greek πολύ-ς /po΄li-s/ much, many and μέρος /΄meros/ part) is a large molecule (macromolecule) composed of repeating structural units typically connected by covalent chemical bonds. While polymer in popular usage suggests plastic, the term actually refers to a large class of natural and synthetic materials with a variety of properties.

Well-known examples of polymers include plastics and proteins. A simple example is polypropylene, whose repeating unit structure is shown at the right. However, polymers are not just limited to having predominantly carbon backbones, elements such as silicon form familiar materials such as silicones, examples being silly putty and waterproof plumbing sealant. The backbone of DNA is in fact based on a phosphodiester bond.

Natural polymer materials such as shellac and amber have been in use for centuries. Biopolymers such as proteins and nucleic acids play crucial roles in biological processes. A variety of other natural polymers exist, such as cellulose, which is the main constituent of wood and paper.

The list of synthetic polymers includes Bakelite, neoprene, nylon, PVC, polystyrene, polyacrylonitrile, PVB, silicone, and many more.

Polymers are studied in the fields of polymer chemistry, polymer physics, and polymer science.

Etymology

The word polymer is derived from the Greek words πολυ (poly), meaning "many"; and μέρος (meros), meaning "part". The term was coined in 1833 by Jöns Jakob Berzelius, although his definition of a polymer was quite different from the modern definition. (see Jöns Jakob Berzelius#New chemical terms)

Historical development

Starting in 1811, Henri Braconnot did pioneering work in derivative cellulose compounds, perhaps the earliest important work in polymer science. The development of vulcanization later in the nineteenth century improved the durability of the natural polymer rubber, signifying the first popularized semi-synthetic polymer. In 1907, Leo Baekeland created the first completely synthetic polymer, Bakelite, by reacting phenol and formaldehyde at precisely controlled temperature and pressure. Bakelite was then publicly introduced in 1909.

Despite significant advances in synthesis and characterization of polymers, a correct understanding of polymer molecular structure did not emerge until the 1920s. Before then, scientists believed that polymers were clusters of small molecules (called colloids), without definite molecular weights, held together by an unknown force, a concept known as association theory. In 1922, Hermann Staudinger proposed that polymers consisted of long chains of atoms held together by covalent bonds, an idea which did not gain wide acceptance for over a decade and for which Staudinger was ultimately awarded the Nobel Prize. Work by Wallace Carothers in the 1920s also demonstrated that polymers could be synthesized rationally from their constituent monomers. An important contribution to synthetic polymer science was made by the Italian chemist Giulio Natta and the German chemist Karl Ziegler, who won the Nobel Prize in Chemistry in 1963 for the development of the Ziegler-Natta catalyst. Further recognition of the importance of polymers came with the award of the Nobel Prize in Chemistry in 1974 to Paul Flory, whose extensive work on polymers included the kinetics of step-growth polymerization and of addition polymerization, chain transfer, excluded volume, the Flory-Huggins solution theory, and the Flory convention.