In chemistry, a metal ( , Μέταλλο) is a chemical element whose atoms readily lose electrons to form positive ions (cations), and form metallic bonds between other metal atoms and ionic bonds between nonmetal atoms.Mortimer, Charles E. Chemistry: A Conceptual Approach. 3rd ed. New York: D. Van Nostrad Company, 1975.
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In chemistry, a metal ( , Μέταλλο) is a chemical element whose atoms readily lose electrons to form positive ions (cations), and form metallic bonds between other metal atoms and ionic bonds between nonmetal atoms.Mortimer, Charles E. Chemistry: A Conceptual Approach. 3rd ed. New York: D. Van Nostrad Company, 1975.
Definition
Metals are sometimes described as a lattice of positive ions surrounded by a cloud of delocalized electrons. They are one of the three groups of elements as distinguished by their ionization and bonding properties, along with the metalloids and nonmetals. On the periodic table, a diagonal line drawn from boron (B) to polonium (Po) separates the metals from the nonmetals. Most elements on this line are metalloids, sometimes called semi-metals; elements to the lower left are metals; elements to the upper right are nonmetals (see the periodic table showing the metals).
An alternative definitionFact: date=August 2008 of metals is that they have overlapping conduction bands and valence bands in their electronic structure. This definition opens up the category for metallic polymers and other organic metals, which have been made by researchers and employed in high-tech devices. These synthetic materials often have the characteristic silvery-grey reflectiveness (luster) of elemental metals.
Chemical properties
Metals are usually inclined to form cations through electron loss, reacting with oxygen in the air to form oxides over changing timescales (iron rusts over years, while potassium burns in seconds). Examples:
- 4Na + O2 → 2Na2O (sodium oxide)
- 2Ca + O2 → 2CaO (calcium oxide)
- 4Al + 3O2 → 2Al2O3 (aluminium oxide)
The transition metals (such as iron, copper, zinc, and nickel) take much longer to oxidize. Others, like palladium, platinum and gold, do not react with the atmosphere at all. Some metals form a barrier layer of oxide on their surface which cannot be penetrated by further oxygen molecules and thus retain their shiny appearance and good conductivity for many decades (like aluminium, some steels, and titanium). The oxides of metals are generally basic (as opposed to those of nonmetals, which are acidic.
Painting, anodising or plating metals are good ways to prevent their corrosion. However, a more reactive metal in the electrochemical series must be chosen for coating, especially when chipping of the coating is expected. Water and the two metals form an electrochemical cell, and if the coating is less reactive than the coatee, the coating actually promotes corrosion.
Physical properties
Density
The majority of metals have higher densities than the majority of nonmetals. Nonetheless, there is wide variation in the densities of metals; lithium is the least dense solid element and osmium is the densest. The metals of groups I A and II A are referred to as the light metals because they are exceptions to this generalization. The high density of most metals is due to the tightly-packed crystal lattice of the metallic structure. The strength of metallic bonds for different metals reaches a maximum around the center of the transition series, as those elements have large amounts of delocalized electrons in a metallic bond. However, other factors (such as atomic radius, nuclear charge, number of bonding orbitals, overlap of orbital energies, and crystal form) are involved as well.
