A heavy metal is a member of an ill-defined subset of elements that exhibit metallic properties, which would mainly include the transition metals, some metalloids, lanthanides, and actinides. Many different definitions have been proposed—some based on density, some on atomic number or atomic weight, and some on chemical properties or toxicity. The term heavy metal has been called "meaningless and misleading" in an IUPAC technical report due to the contradictory definitions and its lack of a "coherent scientific basis".John H. Duffus ""Heavy metals" a meaningless term? (IUPAC Technical Report)" Pure and Applied Chemistry, 2002, Vol. 74, pp. 793-807. doi: 10.1351/pac200274050793 There is an alternative term toxic metal, for which no consensus of exact definition exists either. As discussed below, depending on context, heavy metal can include elements lighter than carbon and can exclude some of the heaviest metals. One source defines heavy metal as one of the "common transition metals, such as copper, lead, and zinc. These metals are a cause of environmental pollution (heavy-metal pollution) from a number of sources, including lead in petrol, industrial effluents, and leaching of metal ions from the soil into lakes and rivers by acid rain." Another common definition is based on the density of the metal (hence the name heavy metal), classifying all metals weighing more than 5000 kg/m3, such as lead, zinc and copper, as heavy metals. Heavy metals occur naturally in the ecosystem with large variations in concentration. Nowadays anthropogenic sources of heavy metals, i.e. pollution, have been introduced to the ecosystem. Waste derived fuels are especially prone to contain heavy metals so they should be a central concern in a consideration of their use.

Relationship to living organisms

Living organisms require varying amounts of "heavy metals." Iron, cobalt, copper, manganese, molybdenum, and zinc are required by humans. Excessive levels can be damaging to the organism. Other heavy metals such as mercury, plutonium, and lead are toxic metals that have no known vital or beneficial effect on organisms, and their accumulation over time in the bodies of animals can cause serious illness. Certain elements that are normally toxic are, for certain organisms or under certain conditions, beneficial. Examples include vanadium, tungsten, and even cadmium.

Heavy metal pollution

Motivations for controlling heavy metal concentrations in gas streams are diverse. Some of them are dangerous to health or to the environment (e.g. Hg, Cd, As, Pb, Cr), some may cause corrosion (e.g. Zn, Pb), some are harmful in other ways (e.g. Arsenic may pollute catalysts). Within European community the 13 elements of highest concern are As, Cd, Co, Cr, Cu, Hg, Mn, Ni, Pb, Sn and Tl, the emissions of which are regulated in waste incinerators. Some of these elements are actually necessary for humans in minute amounts (Co, Cu, Cr, Ni) whilst others are carcinogenic or toxic, affecting, among others, the central nervous system (Hg, Pb, As), the kidneys or liver (Hg, Pb, Cd, Cu) or skin, bones or teeth (Ni, Cd, Cu, Cr).Ron Zevenhoven, Pia Kilpinen: Control of Pollutants in Flue Gases and Fuel Gases. TKK, Espoo 2001.