Formation

If a solid surface is chilled below the dew point of the surrounding air and the surface itself is colder than freezing, frost will form on the surface. Frost consists of spicules of ice which grow out from the solid surface. The size of the crystals depends on time, temperature, and the amount of water vapor available.

In general, for frost to form the deposition surface must be colder than the surrounding air. For instance frost may be observed around cracks in cold wooden sidewalks when moist air escapes from the ground below. Other objects on which frost tends to form are those with low specific heat or high thermal emissivity, such as blackened metals; hence the accumulation of frost on the heads of rusty nails. The apparently erratic occurrence of frost in adjacent localities is due partly to differences of elevation, the lower areas becoming colder on calm nights. It is also affected by differences in absorptivity and specific heat of the ground which in the absence of wind greatly influences the temperature attained by the superincumbent air.

Because cold air is denser than warm air, in calm weather cold air pools at ground level. This is known as surface temperature inversion. It explains why frost is more common and extensive in low-lying areas. Areas where frost forms due to cold air trapped against the ground or against a solid barrier such as a wall are known as "frost pockets".

The formation of frost is an example of meteorological deposition.

Radiation frost

Radiation frost (also called hoar frost or hoarfrost) refers to the white ice crystals, loosely deposited on the ground or exposed objects, that form on cold clear nights when radiation losses into the open skies cause objects to become colder than the surrounding air. A related effect is flood frost which occurs when air cooled by ground-level radiation losses travels downhill to form pockets of very cold air in depressions, valleys, and hollows. Hoar frost can form in these areas even when the air temperature a few feet above ground is well above freezing. Nonetheless the frost itself will be at or below the freezing temperature of water.

Hoar frost may have different names depending on where it forms. For example, air hoar is a deposit of hoar frost on objects above the surface, such as tree branches, plant stems, wires; surface hoar is formed by fernlike ice crystals directly deposited on snow, ice or already frozen surfaces; crevasse hoar consists in crystals that form in glacial crevasses where water vapour can accumulate under calm weather conditions; depth hoar refers to cup shaped, faceted crystals formed within dry snow, beneath the surface.