Dolomite ( ) is the name of a sedimentary carbonate rock and a mineral, both composed of calcium magnesium carbonate CaMg(CO₃)₂ found in crystals.

Dolomite rock (also dolostone) is composed predominantly of the mineral dolomite. Limestone that is partially replaced by dolomite is referred to as dolomitic limestone, or in old U.S. geologic literature as magnesian limestone. Dolomite was first described in 1791 as the rock by the French naturalist and geologist, Déodat Gratet de Dolomieu (1750–1801) for exposures in the Dolomite Alps of northern Italy.

Properties

The mineral dolomite crystallizes in the trigonal-rhombohedral system. It forms white, gray to pink, commonly curved crystals, although it is usually massive. It has physical properties similar to those of the mineral calcite, but does not rapidly dissolve or effervesce (fizz) in dilute hydrochloric acid unless it is scratched or in powdered form. The Mohs hardness is 3.5 to 4 and the specific gravity is 2.85. Refractive index values are nω = 1.679 - 1.681 and nε = 1.500. Crystal twinning is common. A solid solution series exists between dolomite and iron rich ankerite. Small amounts of iron in the structure give the crystals a yellow to brown tint. Manganese substitutes in the structure also up to about three percent MnO. A high manganese content gives the crystals a rosy pink color noted in the image above. A series with the manganese rich kutnohorite may exist. Lead and zinc also substitute in the structure for magnesium.

Formation

Modern dolomite does occur as a precipitating mineral in specialized environments on the surface of the earth today. In the 1950s and 60s, dolomite was found to be forming in highly saline lakes in the Coorong region of South Australia. Dolomite crystals also occur in deep-sea sediments, where organic matter content is high. This dolomite is termed "organogenic" dolomite.

Recent research has found modern dolomite formation under anaerobic conditions in supersaturated saline lagoons along the Rio de Janeiro coast of Brazil, namely, Lagoa Vermelha and Brejo do Espinho. One interesting reported case was the formation of dolomite in the kidneys of a Dalmatian dog. This was believed to be due to chemical processes triggered by bacteria. Dolomite has been speculated to develop under these conditions with the help of sulfate-reducing bacteria. This joins other research in pointing out many new interesting links between large-scale geology and small-scale microbiology (see geomicrobiology).