Direct combustion by atmospheric oxygen is a reaction mediated by radical intermediates. The conditions for radical production are naturally produced by thermal runaway, where the heat generated by combustion is necessary to maintain the high temperature necessary for radical production.
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Direct combustion by atmospheric oxygen is a reaction mediated by radical intermediates. The conditions for radical production are naturally produced by thermal runaway, where the heat generated by combustion is necessary to maintain the high temperature necessary for radical production.
In a complete combustion reaction, a compound reacts with an oxidizing element, such as oxygen or fluorine, and the products are compounds of each element in the fuel with the oxidizing element. For example:
- chem: 4 + 2chem: 2 → chem: 2 + 2
- + 6chem: 2 → chem: 4 + 2chem: HF + chem: 6
- 2chem: 2 + chem: 2 → 2 (g) + heat
- chem: 4 + 2chem: 2 + 7.52chem: 2 → chem: 2 + 2 + 7.52chem: 2 + heat
A simpler example can be seen in the combustion of hydrogen and oxygen, which is a commonly used reaction in rocket engines:
The result is water vapor.
In the large majority of the real world uses of combustion, the oxygen (O2) oxidant is obtained from the ambient air and the resultant flue gas from the combustion will contain nitrogen:
As can be seen, when air is the source of the oxygen, nitrogen is by far the largest part of the resultant flue gas.
In reality, combustion processes are never perfect or complete. In flue gases from combustion of carbon (as in coal combustion) or carbon compounds (as in combustion of hydrocarbons, wood etc.) both unburned carbon (as soot) and carbon compounds (CO and others) will be present. Also, when air is the oxidant, some nitrogen can be oxidized to various nitrogen oxides (NOx).
Rapid
Rapid combustion is a form of combustion in which large amounts of heat and light energy are released, which often results in a fire. This is used in a form of machinery such as internal combustion engines and in thermobaric weapons. Sometimes, a large volume of gas is liberated in combustion besides the production of heat and light. The sudden evolution of large quantities of gas creates excessive pressure that produces a loud noise. Such a combustion is known as an explosion.
Slow
Slow combustion is a form of combustion which takes place at low temperatures. Cellular respiration is an example of slow combustion.
Complete
In complete combustion, the reactant will burn in oxygen, producing a limited number of products. When a hydrocarbon burns in oxygen, the reaction will only yield carbon dioxide and water. When a hydrocarbon or any fuel burns in air, the combustion products will also include nitrogen. When elements such as carbon, nitrogen, sulfur, and iron are burned, they will yield the most common oxides. Carbon will yield carbon dioxide. Nitrogen will yield nitrogen dioxide. Sulfur will yield sulfur dioxide. Iron will yield iron(III) oxide. It should be noted that complete combustion is almost impossible to achieve. In reality, as actual combustion reactions come to equilibrium, a wide variety of major and minor species will be present. For example, the combustion of methane in air will yield, in addition to the major products of carbon dioxide and water, the minor product carbon monoxide and nitrogen oxides, which are products of a side reaction (oxidation of nitrogen).
