In geography and geology, a cliff is a significant vertical, or near vertical, rock exposure. Cliffs are formed as erosion landforms due to the processes of erosion and weathering that produce them. Cliffs are common on coasts, in mountainous areas, escarpments and along rivers. Cliffs are usually formed by rock that is resistant to erosion and weathering. Sedimentary rocks most likely to form sandstone, limestone, chalk, and dolomite. Igneous rocks, such as granite and basalt also often form cliffs.

An escarpment (or scarp) is a type of cliff, formed by the movement of a geologic fault, or a landslide.

Most cliffs have some form of scree slope at their base. In arid areas or under high cliffs, these are generally exposed jumbles of fallen rock. In areas of higher moisture, a soil slope may obscure the talus.

Many cliffs also feature tributary waterfalls or rock shelters. Sometimes a cliff peters out at the end of a ridge, with tea tables or other types of rock columns remaining.

Given that a cliff need not be exactly vertical, there can be ambiguity about whether a given slope is a cliff or not, and also about how much of a certain slope to count as a cliff. (For example, given a truly vertical rock wall above a very steep slope, one could count only the rock wall, or the combination.) This makes listings of cliffs an inherently uncertain endeavor.

The highest cliff (rock wall, mountain face) in the world, is Nanga Parbat's Rupal Flank in the Himalayas, that rises 4600 meters above its base.

According to some sources, the highest cliff in the world, about 1,340 m high, is the east face of Great Trango in the Karakoram mountains of northern Pakistan. (This uses a fairly stringent notion of cliff, as the 1,340 m figure refers to a nearly vertical headwall; adding in a very steep approach brings the total height to over 1,600 m.) The highest sea cliffs, 1,010 m high, are located at Kalaupapa, Hawaii. (This uses a less stringent definition, as the average slope of these cliffs is about 1.7, corresponding to an angle of 60 degrees.)

Considering a truly vertical drop, Mount Thor on Baffin Island in Arctic Canada is often considered the highest at 1,370 m (4,500 ft) high in total (the top 480 m (1,600 ft) is overhanging), and is said to give it the longest purely vertical drop on Earth at 1,250 m (4,100 ft). There is some doubt as to whether this height is exceeded by other cliffs on Baffin Island or in Greenland, however.

The Ordnance Survey distinguish between cliffs (continuous line along the top edge with projections down the face) and outcrops (continuous lines along lower edge).