Venetian chevron beads are drawn beads, made from glass canes which are created in specifically constructed star moulds. The first chevron beads were made towards the end of the 15th century, consisting of 7 layers of alternating colours. They usually have 6 facets. Unlike their later counterparts they were not always made with the standard 12-point star mould. By the beginning of the 20th century, 4 and 6-layer chevron beads appear on various sample cards. According to records kept at the Societa Veneziana Conterie of Murano, they stopped making chevron canes during the 1950s. Chevron beads are still being made in Venice today, albeit in very small quantities only.

Chevron beads can be composed of a varied number of consecutive layers of colored glasses. The initial core is formed from a molten ball of glass (called a "gather") that was melted in a furnace. If the glassworker is making beads, an air bubble is blown into the center of the gather via a blowpipe, thus creating an opening, the future bead's perforation. When making solid multilayered cane intended to be used for decorating millefiori beads, no air bubble is inserted. The gather (with the air bubble in its center) is plunged into a star-shaped mould, which can have anywhere between five and fifteen points. Several layers of glass can be applied, returning to the mould as desired, to create either a star-shaped or smooth effect for each layer. After all layers have been applied, metal plates are affixed to the still hot glass, which is "drawn" or stretched out into a long rod, called a "cane", by pulling from both ends in opposite directions. The bubble at the center of the gather stretches with the cane and forms the hole in the bead, i.e. the bead's perforation. The diameter of the cane, and therefore of the resulting beads, is determined by the amount of glass in the original gather and also by how thin the glass is drawn out. The cooled glass cane is cut into short segments which reveal a star pattern in cross-section. The segments may be beveled or ground, to reveal the characteristic chevron pattern from which the English name is derived. The chevron pattern becomes apparent after the beads' ends have been ground. Only rosetta/star beads with ground ends (either faceted, rounded, or chamfered), and with their inner layers exposed, are "chevron" beads. All star beads with flat ends are more aptly termed rosetta/star beads.

When the bead making industries in India began making chevron beads during the 1980s, the star beads made in Purdalpur, one of the glass bead making centers, were made without the use of a mould, from prepared sections of hot strips of glass that were composited together to form a cane. Because of this method of manufacture, the points of the stars of these beads typically have slight indentations.